In general, a database system will not operate properly if it exist some null values of attributes in the system. In this paper, we propose a new approach to estimate null values in relational database, which utilize other clustering algorithm to cluster data, and use fuzzy correlation and distance similarity to calculate the correlation of different attribute. For verifying our method, this paper utilize mean of absolute error rate (MAER) as evaluation criterion to compare with other methods; it is shown that our proposed method proves importance than the existing methods for estimating null values in relational database systems.